1) Login to the web interface as administrator through URL : mail.yourdomainname.com with administrator username with password

Note: The email account need to have administrator privilege in order to reset email account password from Smartermail

2) Go to the last button of the top panel > Domain Settings

3) Select the Accounts on Left panel

4) Click on the email account from email account list then click on … button and Change Password

5) Change the password and save it.